Heat and Mass Transfer in Hygroscopic Porous Media: Consequences of Invoking Tóth’s Sorption Isotherm

نویسندگان

چکیده

Abstract The thermal performance of ventilated beds hygroscopic porous media depends strongly on the sorption properties solid phase. Furthermore, published literature shows that predicted is extremely sensitive to form and accuracy isotherm. This particularly apparent under idealized conditions when thermodynamic equilibrium deemed exist between fluid phases. When Tóth’s isotherm invoked in an model used analyse a bed initially warm dry silica gel with cool, humid air, it shock wave develops downstream air entering bed. In contrast, shown non-equilibrium solutions result transfer wave, width which decreases as velocity interstitial decreases. Tóth gives rise erroneous values integral heat wetting gel. Previously studies simultaneous mass materials refer conceptual difficulties interpreting results, some mathematical analyses are somewhat terse. A secondary aim this work assuage these by detailing Supplementary Information.

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ژورنال

عنوان ژورنال: Transport in Porous Media

سال: 2023

ISSN: ['0169-3913', '1573-1634']

DOI: https://doi.org/10.1007/s11242-023-01931-7